全文获取类型
收费全文 | 13857篇 |
免费 | 3126篇 |
国内免费 | 3110篇 |
专业分类
化学 | 10420篇 |
晶体学 | 412篇 |
力学 | 933篇 |
综合类 | 278篇 |
数学 | 1602篇 |
物理学 | 6448篇 |
出版年
2024年 | 16篇 |
2023年 | 315篇 |
2022年 | 498篇 |
2021年 | 664篇 |
2020年 | 734篇 |
2019年 | 696篇 |
2018年 | 610篇 |
2017年 | 617篇 |
2016年 | 708篇 |
2015年 | 876篇 |
2014年 | 975篇 |
2013年 | 1184篇 |
2012年 | 1363篇 |
2011年 | 1346篇 |
2010年 | 1066篇 |
2009年 | 1167篇 |
2008年 | 1175篇 |
2007年 | 1022篇 |
2006年 | 908篇 |
2005年 | 744篇 |
2004年 | 554篇 |
2003年 | 429篇 |
2002年 | 388篇 |
2001年 | 349篇 |
2000年 | 369篇 |
1999年 | 254篇 |
1998年 | 152篇 |
1997年 | 110篇 |
1996年 | 117篇 |
1995年 | 81篇 |
1994年 | 80篇 |
1993年 | 79篇 |
1992年 | 66篇 |
1991年 | 42篇 |
1990年 | 54篇 |
1989年 | 49篇 |
1988年 | 35篇 |
1987年 | 43篇 |
1986年 | 36篇 |
1985年 | 33篇 |
1984年 | 24篇 |
1983年 | 16篇 |
1982年 | 9篇 |
1981年 | 6篇 |
1980年 | 6篇 |
1979年 | 9篇 |
1978年 | 4篇 |
1976年 | 3篇 |
1966年 | 2篇 |
1957年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 296 毫秒
991.
本文采用传统固相反应法,成功制备了新型无铅弛豫铁电陶瓷(1-x)[0.9BaTiO3-0.1Bi(Mg0.25Ta0.5)O3]-xBi0.5Na0.5TiO3。结果表明,较高居里温度的Bi0.5Na0.5TiO3的引入,使得材料体系中建立了更多的以Bi—O耦合为主的极性纳米区域,弥补了因Bi(Mg0.25Ta0.5)O3的加入导致的宏观极化强度的减少,提高了材料的饱和极化强度,实现了较高储能密度的同时具有更好的温度稳定性。在245 kV/cm电场强度下,x=0.2样品的储能密度约为4.01 J/cm3,储能效率约为84.86%,同时该组分在20~170 ℃储能密度的变化率小于5%,储能效率的变化率小于6%,表现出优异的温度稳定性。 相似文献
992.
High‐Loading Nano‐SnO2 Encapsulated in situ in Three‐Dimensional Rigid Porous Carbon for Superior Lithium‐Ion Batteries 下载免费PDF全文
Hairong Xue Dr. Jianqing Zhao Jing Tang Hao Gong Prof. Ping He Prof. Haoshen Zhou Prof. Yusuke Yamauchi Prof. Jianping He 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(14):4915-4923
Tin oxide nanoparticles (SnO2 NPs) have been encapsulated in situ in a three‐dimensional ordered space structure. Within this composite, ordered mesoporous carbon (OMC) acts as a carbon framework showing a desirable ordered mesoporous structure with an average pore size (≈6 nm) and a high surface area (470.3 m2 g?1), and the SnO2 NPs (≈10 nm) are highly loaded (up to 80 wt %) and homogeneously distributed within the OMC matrix. As an anode material for lithium‐ion batteries, a SnO2@OMC composite material can deliver an initial charge capacity of 943 mAh g?1 and retain 68.9 % of the initial capacity after 50 cycles at a current density of 50 mA g?1, even exhibit a capacity of 503 mA h g?1 after 100 cycles at 160 mA g?1. In situ encapsulation of the SnO2 NPs within an OMC framework contributes to a higher capacity and a better cycling stability and rate capability in comparison with bare OMC and OMC ex situ loaded with SnO2 particles (SnO2/OMC). The significantly improved electrochemical performance of the SnO2@OMC composite can be attributed to the multifunctional OMC matrix, which can facilitate electrolyte infiltration, accelerate charge transfer, and lithium‐ion diffusion, and act as a favorable buffer to release reaction strains for lithiation/delithiation of the SnO2 NPs. 相似文献
993.
994.
不同变质程度煤的高分辨率透射电镜分析 总被引:1,自引:0,他引:1
不同变质程度煤的高分辨率透射电镜分析 《燃料化学学报》2016,44(3):279-286
利用高分辨率透射电子显微镜(HRTEM)分析了三种不同变质程度煤样的结构特征。基于傅里叶-反傅里叶变换方法,并结合Matlab、Arcgis和Auto CAD软件,通过图像分析技术,获得了HRTEM照片的晶格条纹参数。结果表明,三种煤样的晶格条纹呈现不同特征,按条纹长度分别归属于1×1-8×8共计八个类型。以3×3为临界点,在1×1和2×2中,ML-8中芳香层片的比例高于DP-4和XM-3;在3×3-8×8中,ML-8中芳香层片的比例低于DP-4和XM-3。对比HRTEM和XRD参数d002发现,随着镜质组反射率的增加d002都呈现递减趋势。 相似文献
995.
Jinhua Ji Hao Liu Zewei Chen Yajun Fu Prof. Weijun Yang Prof. Shuang-Feng Yin 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(43):11102-11109
Metal-organic framework (MOF) is an ideal precursor/template for porous carbon, and its active components are uniformly doped, which can be used in energy storage and catalytic conversion fields. Metal-organic framework PCN-224 with carboxylporphyrin as the ligand was synthesized, and then Zn2+ and Co2+ ions were coordinated in the center of the porphyrin ring by post-modification. Here, PCN-224−ZnCo with different ratios of bimetallic Zn2+/Co2+ ions were used as the precursor, and the metal-nitrogen-carbon(M−N−C) material of PCN-224−ZnCo-950 was obtained by pyrolyzing the precursor at 950 °C in Ar. Because Zn is easy to volatilize at 950 °C, the formed M−N−C materials can reflect different Co contents and different basic site concentrations. The formed material still maintains the original basic framework. With the increase of Zn2+/Co2+ ratio in precursor, the concentration of N-containing alkaline sites in pyrolysis products gradually increase. Compared with the precursor, PCN-224−ZnCo1-950 with Zn2+/Co2+=1 : 1 has greatly improved basicity and suitable acidic/ alkaline site concentration. It can be efficiently used to carbon dioxide absorption and catalyze the cycloaddition of CO2 with epoxide. More importantly, the current method of adjusting the acidic/basic sites in M−N−C materials through volatilization of volatile metals can provide an effective strategy for adjusting the catalysis of MOF derivatives with porphyrin structure. 相似文献
996.
997.
998.
Aimin Hao Xiaocui Yang Chunxiao Gao Yonghao Han Yongjun Tian 《Journal of Physics and Chemistry of Solids》2009,70(2):433-438
A theoretical investigation on the structural stabilities and electronic properties of HgTe under high pressure was conducted using first principles based on density functional theory. Our results demonstrate that the sequence of the pressure-induced phase transitions of HgTe is from the zinc blende, to cinnabar, rocksalt, orthorhombic, and CsCl-type structures. The pressure effects on the optical properties were discussed and compared with previous calculations and experimental data whenever available. 相似文献
999.
Entanglement Purification for Mixed Entangled Quantum Dot States via Superconducing Transmission Line Resonators 下载免费PDF全文
An entanglement purification protocol for mixed entangled states is presented via double quantum dot molecules inside a superconducing transmission line resonator (TLR). In the current scenario, coupling for arbitrary double quantum dot molecules can be tuned via the TLR in the large detuning region by controlling the qubit level splitting. The TLR is always empty and only virtually excited, so the interaction is insensitive to both the TLR decay and thermal field. Discussion about the feasibility of our scheme shows that the entanglement purification can be implemented with high fidelity and successful probability. 相似文献
1000.
In this paper, we investigate the convergence of the proximal iteratively reweighted algorithm for a class of nonconvex and nonsmooth problems. Such problems actually include numerous models in the area of signal processing and machine learning research. Two extensions of the algorithm are also studied. We provide a unified scheme for these three algorithms. With the Kurdyka–?ojasiewicz property, we prove that the unified algorithm globally converges to a critical point of the objective function. 相似文献